Spider-Man 2099 #24
In "Assault and Batteries," Kasey unleashes her new powers as Payback in a bold strike against Alchemax—only to be swiftly overwhelmed by the deadly Risque. As Spider-Man fights to hold his ground, he’s forced to resort to his venom to subdue her, pushing him to his limits. Just when it seems hopeless, Venture arrives on the scene, shifting the tide in unpredictable ways. Written by Peter David and illustrated by Rick Leonardi, with inks by Al Williamson, colors by Steve Buccellato, and letters by Ken Lopez, this 1994 issue features a cover by Rick Leonardi and Al Williamson.
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Kasey uses her new powers to attack Alchemax as Payback, only to get creamed by Risque before she can really do anything. Risque then takes down Spider-Man, and he only defeats her by using his venom to poison her. Then Venture appears.
Plot details indexed by the Grand Comics Database (CC BY-SA).